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A systematic examine of the expansion technique is carried out by substituting As and Sb for P in the group-V provider gas. Reactions of Al(BH4)three with AsH3 at 320 °C yielded the expected BAs films with small amounts of Al. In this case the samples are amorphous and efforts to crystallize them by growing the expansion temperature yielded boron-rich analogues. Analogous reactions of Al(BH4)3 with SbD3 on Si at 300 °C produce AlSb epitaxial crystals doped with B instead of the BSb part.

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